Kinetics of Inhibition of Dichlorophenol Oxidation by NaCl over Fe-Cu-Pillared Clay

Influence of Operational Parameters and Kinetic Modelling of Catalytic Wet Air Oxidation of Phenol by Al/Zr Pillared Clay Catalyst

Single and mixed oxide Al/Zr-pillared clay (Al/Zr-PILC) catalysts were synthesized and tested for catalytic wet air oxidation (CWAO) of aqueous phenol solution under milder conditions, in a semi-batch reactor. The catalysts were synthesized from natural bentonite clay using ultrasonic treatment during the aging and intercalation steps and were characterized <...

Inhibition of Copper Corrosion by Ethanolamine in 100 ppm NaCl

We study copper corrosion inhibition by ethanolamine (ETA)with (0, 0.2 ,0.3,0.4,0.5) vol.% concentrations in 100 ppm NaCl solution. This work is carried out by potentiodynamic measurements and Electrochemical Impedance Spectroscopy (EIS). The substrates' surface morphologies are examined by Scanning Electron Microscopy (...

Room Temperature Oxidation of Al-Cu-Fe and Al-Cu-Fe-Cr Quasicrystals

We have investigated formation of oxides on quasicrystalline and crystalline alloy surfaces of similar composition, in different oxidizing environments. This includes a comparison between a quaternary orthorhombic approximate of Al-Cu-Fe-Cr quasicrystal and the ternary AI-Cu-Fe quasicrystalline and crystalline phases. We noted that each sample showed the following common trends: preferential ox...

Thermodynamics and Kinetics of Vaporization of Pbs From Complex Cu-Fe Mattes

Thermodynamics and kinetics of vaporization of lead sulfide from typical copper-smelting mattes of commercial interest are investigated in the temperature range 1388 K to 1573 K by vapor transport technique and plasma arc spectroscopy. The total mass of the dominant vaporizing species PbS that leaves the matte is described by the Newman's numerical solution to the second Fick's law combined wit...

Kinetics and Mechanism of Inhibition of Oxidation Enzymes by Herbicides